La Liga 12 Ağustos tarihinde ilk karşılaşma ile başlamış olacak. 26 Mayıs 2023 tarihinde ise son hafta oynanacak ve lig sona erecek. İlk hafta fikstürü şu şekilde olacak;
| 12.08.2023 | Athletic Bilbao | v | Real Madrid |
| 19.08.2023 | Almeria | v | Real Madrid |
| 27.08.2023 | Celta Vigo | v | Real Madrid |
| 03.09.2023 | Real Madrid | v | Getafe |
| 17.09.2023 | Real Madrid | v | Real Sociedad |
| 24.09.2023 | Atletico Madrid | v | Real Madrid |
| 27.09.2023 | Real Madrid | v | Las Palmas |
| 01.10.2023 | Girona | v | Real Madrid |
| 08.10.2023 | Real Madrid | v | Osasuna |
| 22.10.2023 | Sevilla | v | Real Madrid |
| 29.10.2023 | Barcelona | v | Real Madrid |
| 05.11.2023 | Real Madrid | v | Rayo Vallecano |
| 12.11.2023 | Real Madrid | v | Valencia |
| 26.11.2023 | Cadiz | v | Real Madrid |
| 03.12.2023 | Real Madrid | v | Granada |
| 10.12.2023 | Real Betis | v | Real Madrid |
| 17.12.2023 | Real Madrid | v | Villarreal |
| 20.12.2023 | Alaves | v | Real Madrid |
| 03.01.2024 | Real Madrid | v | Mallorca |
| 14.01.2024 | Getafe | v | Real Madrid |
| 21.01.2024 | Real Madrid | v | Almeria |
| 28.01.2024 | Las Palmas | v | Real Madrid |
| 04.02.2024 | Real Madrid | v | Atletico Madrid |
| 11.02.2024 | Real Madrid | v | Girona |
| 18.02.2024 | Rayo Vallecano | v | Real Madrid |
| 25.02.2024 | Real Madrid | v | Sevilla |
| 03.03.2024 | Valencia | v | Real Madrid |
| 10.03.2024 | Real Madrid | v | Celta Vigo |
| 17.03.2024 | Osasuna | v | Real Madrid |
| 31.03.2024 | Real Madrid | v | Athletic Bilbao |
| 14.04.2024 | Mallorca | v | Real Madrid |
| 21.04.2024 | Real Madrid | v | Barcelona |
| 28.04.2024 | Real Sociedad | v | Real Madrid |
| 05.05.2024 | Real Madrid | v | Cadiz |
| 12.05.2024 | Granada | v | Real Madrid |
| 15.05.2024 | Real Madrid | v | Alaves |
| 19.05.2024 | Villarreal | v | Real Madrid |
| 26.05.2024 | Real Madrid | v | Real Betis |